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Select File > Save As > OneDrive - [company name] to save a work file to OneDrive.
Save personal files to OneDrive - Personal.
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Select File > Open and then select OneDrive, to open a file saved to OneDrive.
Direct Link For more information: https://support.office.com/en-us/article/upload-and-save-files-and-folders-to-onedrive-for-business-a1397e56-61ec-4ed2-9dac-727bf8ac3357